From insulator to conductor in a flash

A clever combination of novel technologies enables us to study promising materials for the electronics of tomorrow. Over the past decades, computers have become faster and faster and hard disks and storage chips have reached enormous capacities. But this trend cannot continue forever: we are already running up against physical limits that will prevent silicon-based computer technology from attaining any impressive speed gains from this point on. Researchers are particularly optimistic that the next era of technological advancements will start with the development of novel information-processing materials and technologies that combine electrical circuits with optical ones. Using short laser pulses, a research team led by Misha Ivanov of the Max Born Institute in Berlin together with scientists from the Russian Quantum Center in Moscow have now shed light on the extremely rapid processes taking place within these novel materials. Their results have appeared in the prestigious journal "Nature Photonics".

Of particular interest for modern material research in solid state physics are "strongly correlated systems", so called for the strong interactions between the electrons in these materials. Magnets are a good example of this: the electrons in magnets align themselves in a preferred direction of spin inside the material, and it is this that produces the magnetic field. But there are other, entirely different structural orders that deserve attention. In so-called Mott insulators for example, a class of materials now being intensively researched, the electrons ought to flow freely and the materials should therefore be able to conduct electricity as well as metals. But the mutual interaction between electrons in these strongly correlated materials impedes their flow and so the materials behave as insulators instead.

By disrupting this order with a strong laser pulse, the physical properties can be made to change dramatically. This can be likened to a phase transition from solid to liquid: as ice melts, for example, rigid ice crystals transform into free-flowing water molecules. Very similarly, the electrons in a strongly correlated material become free to flow when an external laser pulse forces a phase transition in their structural order. Such phase transitions should allow us to develop entirely new switching elements for next-generation electronics that are faster and potentially more energy efficient than present-day transistors. In theory, computers could be made around a thousand times faster by "turbo-charging" their electrical components with light pulses.

High harmonic spectroscopy of light-induced phase transition. The vertical red line shows when the laser electric field (yellow oscillating curve) crosses the threshold field, destroying the insulating phase of the material. The top panel shows the average number of doublon-hole pairs per site (blue) and the decay of the insulating field-free ground state (red). (Source: MBI)

The problem with studying these phase transitions is that they are extremely fast and it is therefore very difficult to "catch them in the act". So far, scientists have had to content themselves with characterising the state of a material before and after a phase transition of this kind. Researchers Rui E. F. Silva, Olga Smirnova, and Misha Ivanov of the Berlin Max Born Institute, however, have now devised a method that will, in the truest sense, shed light on the process. Their theory involves firing extremely short, tailored laser pulses at a material - pulses that can only recently be produced in the appropriate quality given the latest developments in lasers. One then observes the material's reaction to these pulses to see how the electrons in the material are excited into motion and, like a bell, emit resonant vibrations at specific frequencies, as harmonics of the incident light.

"By analysing this high harmonic spectrum, we can observe the change in the structural order in these strongly correlated materials 'live' for the first time," says first author of the paper Rui Silva of the Max Born Institute. Laser sources capable of targetedly triggering these transitions have only been available since very recently. The laser pulses namely have to be amply strong and extremely short - on the order of femtoseconds in duration (millionths of a billionth of a second).

In some cases, it takes only a single oscillation of light to disrupt the electronic order of a material and turn an insulator into a metal-like conductor. The scientists at the Berlin Max Born Institute are among the world's leading experts in the field of ultrashort laser pulses.

"If we want to use light to control the properties of electrons in a material, then we need to know exactly how the electrons will react to light pulses," Ivanov explains. With the latest-generation laser sources, which allow full control over the electromagnetic field even down to a single oscillation, the newly published method will allow deep insights into the materials of the future.

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Publications since 2025

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A1-P-2025.01
Melting, bubblelike expansion, and explosion of superheated plasmonic nanoparticles

S. Dold, T. Reichenbach, A. Colombo, J. Jordan, I. Barke, P. Behrens, N. Bernhardt, J. Correa, S. Düsterer, B. Erk, T. Fennel, L. Hecht, A. Heilrath, R. Irsig, N. Iwe, P. Kolb, B. Kruse, B. Langbehn, B. Manschwetus, P. Marienhagen, F. Martinez, K.-H. Meiwes-Broer, K. Oldenburg, C. Passow, C. Peltz, M. Sauppe, F. Seel, R. M. P. Tanyag, R. Treusch, A. Ulmer, S. Walz, M. Moseler, T. Möller, D. Rupp, B. v. Issendorff

Physical review letters 134 (2025) 136101/1-7

URL, DOI or PDF

A3-P-2025.01
Second-harmonic generation in OP-GaAs0.75P0.25 heteroepitaxially grown from the vapor phase

L. Wang, S. R. Vangala, S. Popien, M. Beutler, J. M. Mann, V. L. Tassev, E. Büttner, V. Petrov

CrystEngComm 27 (2025) 1373-1376

URL, DOI or PDF

A3-P-2025.02
Diode-pumped Kerr-lens mode-locked Yb:MgWO4 laser

H.-Y. Nie, Z.-L. Lin, P. Loiko, H.-J. Zeng, L. Zhang, Z. Lin, G. Z. Elabedine, X. Mateos, V. Petrov, G. Zhang, W. Chen

Optics Letters 50 (2025) 1049-1052

URL, DOI or PDF

A3-P-2025.03
Growth, anisotropy, and spectroscopy of Tm3+ and Yb3+ doped MgWO4 crystals

G. Z. Elabedine, R. M. Solé, S. Slimi, M. Aguiló, F. Díaz, W. Chen, V. Petrov, X. Mateos

CrystEngComm 27 (2025) 1619-1631

URL, DOI or PDF

A3-P-2025.04
Growth, structure, spectroscopic, and laser properties of Ho-doped yttrium gallium garnet crystal

S. Slimi, H. Yu, H. Zhang, C. Kränkel, P. Loiko, R. M. Solé, M. Aguiló, F. Díaz, W. Chen, U. Griebner, V. Petrov, X. Mateos

Optics Express 33 (2025) 2529-2541

URL, DOI or PDF

A3-P-2025.05
Growth, spectroscopy and laser operation of disordered Tm,Ho:NaGd (MoO4)2 crystal

G. Z. Elabedine, Z. Pan, P. Loiko, H. Chu, D. Li, K. Eremeev, K. Subbotin, S. Pavlov, P. Camy, A. Braud, S. Slimi, R. M. Solé, M. Aguiló, F. Díaz, W. Chen, U. Griebner, V. Petrov, X. Mateos

Journal of Alloys and Compounds 1020 (2025) 179211/1-12

URL, DOI or PDF

A3-P-2025.06
Kerr-lens mode-locked, diode-pumped Yb,Gd:YAP laser generating 23 fs pulses

H.-Y. Nie, P. Zhang, P. Loiko, Z.-L. Lin, H.-J. Zeng, G. Zhang, Z. Li, X. Mateos, H.-C. Liang, V. Petrov, Z. Chen, W. Chen

Optics Express 33 (2025) 11793-11799

URL, DOI or PDF

A3-P-2025.07
Nanoindentation and laser-induced optical damage tests of CdSe nonlinear crystals

G. Exner, A. Carpenter, K. Cissner, A. Hildenbrand-Dhollande, S. Schmitt, A. Grigorov, M. Piotrowski, S. Guha, V. Petrov

Journal of the Optical Society of America B 42 (2025) A10-A14

URL, DOI or PDF

A3-P-2025.08
Phase-matching properties of AgGa(Se1-xTex)2 for SHG of a CO2 laser

K. Kato, V. Petrov, K. Miyata

Proceedings of SPIE 13347 (2025) 133470S/1-4

URL, DOI or PDF

A3-P-2025.09
Phase-matching properties of ZnSiAs2 in the mid-IR

T. Okamoto, N. Umemura, K. Kato, V. Petrov

Proceedings of SPIE 13347 (2025) 133470C/1-5

URL, DOI or PDF

A3-P-2025.10
Direct generation of 3.5 optical-cycle pulses from a rare-earth laser

N. Zhang, Y. Wang, H. Ding, F. Liang, Y. Zhao, J. Xu, H. Yu, H. Zhang, V. Petrov

Optics Letters 50 (2025) 3150-3153

URL, DOI or PDF

A3-P-2025.11
Power scaling of a non-resonant optical parametric oscillator based on periodically poled LiNbO3 with spectral narrowing

S. Das, T. Temel, G. Spindler, A. Schirrmacher, I. B. Divliansky, R. T. Murray, M. Piotrowski, L. Wang, W. Chen, O. Mhibik, V. Petrov

Optics Express 33 (2025) 5662-5669

URL, DOI or PDF

A3-P-2025.12
Sub-40-fs diode-pumped ytterbium-doped mixed rare-earth calcium oxoborate laser

H.-J. Zeng, Z.-L. Lin, H. Lin, P. Loiko, L. Zhang, Z. Lin, H.-C. Liang, X. Mateos, V. Petrov, G. Zhang, W. Chen

Optics Express 33 (2025) 17965-17975

URL, DOI or PDF

A3-P-2025.13
Spectroscopy and SESAM mode-locking of a disordered Yb:Gd2SrAl2O7 crystal

H.-J. Zeng, Z.-L. Lin, P. Loiko, F. Yuan, G. Zhang, Z. Lin, X. Mateos, V. Petrov, W. Chen

Optics Express 33 (2025) 15057-15066

URL, DOI or PDF

A3-P-2025.14
Watt-level, 1.6 ps χ(2)-lens mode-locking of an in-band pumped Nd:LuVO4 laser

H. Iliev, V. Aleksandrov, V. Petrov, L. S. Petrov, H. Zhang, H. Yu, I. Buchvarov

Optics Express 33 (2025) 17773-17781

URL, DOI or PDF

A3-P-2025.15
Refined phase-matching predictions for AgGa1-xInxS2 mixed chalcopyrite crystals

K. Kato, K. Miyata, V. Petrov

Journal of the Optical Society of America B 42 (2025) A6-A9

URL, DOI or PDF

A3-P-2025.16
35-fs diode-pumped mode-locked ytterbium-doped multi-component alkaline-earth fluoride laser

Z. Zhang, Z.-Q. Li, P. Loiko, H.-J. Zeng, G. Zhang, Z.-L. Lin, S. Normani, A. Braud, F. Ma, X. Mateos, H.-C. Liang, V. Petrov, D. Jiang, L. Su, W. Chen

Optics Letters 50 (2025) 1835-1838

URL, DOI or PDF

A3-P-2025.17
Diode-pumped few-optical-cycle laser based on an ytterbium-doped disordered strontium yttrium borate crystal

H. Zeng, Z. Lin, S. Sun, P. Loiko, H. Lin, G. Zhang, Z. Lin, C. Mou, X. Mateos, V. Petrov, W. Chen

Optics Letters 50 (2025) 2203-2206

URL, DOI or PDF

A3-P-2025.18
Refined Sellmeier and thermo-optic dispersion formulas for CdGeAs2

K. Kato, K. Miyata, V. Petrov

Journal of the Optical Society of America B 42 (2025) A24-A28

URL, DOI or PDF

A3-P-2025.19
Diode-pumped mode-locked Yb:Ca3La2(BO3)4 laser generating 35 fs pulses

H.-J. Zeng, Z.-L. Lin, G. Zhang, Z. Pan, P. Loiko, X. Mateos, V. Petrov, H. Lin, W. Chen

Optics Express 33 (2025) 22988-22996

URL, DOI or PDF