Electron ping-pong in the nanoworld

For the first time, an international research team has succeeded in controlling and observing strongly accelerated electrons on nanospheres with extremely short and intense laser pulses.

When strong laser light encounters electrons in nanoparticles that are made up of many millions of atoms, electrons can be released and greatly accelerated. Such an effect in quartz nanospheres has now been recorded by an international research team in the Laboratory for Attosecond Physics (LAP) at the Max Planck Institute of Quantum Optics. The researchers observed how strong electric fields (near fields) in the vicinity of the nanoparticles were built up in the laser light and released electrons - the nanoparticles are ionized in the laser light.

Fig. 1: Mechanism of acceleration of electrons on glass nanospheres. The laser field (red wave) leads to the release of electrons (green particles), which are then moved away from the nanoparticle by the laser field and then accelerated back again.
After an elastic collision with the surface of the nanosphere, very high energies are finally achieved for the released electrons. The picture shows three snapshots of the acceleration (from left to right): 1) the electrons are stopped and return to the surface, 2) the electrons collide elastically with the surface and bounce off and 3) the electrons become very strong accelerated away from the nanosphere.
Christian Hackenberger / LMU

With the help of the near fields and collective interactions of the resulting charges, released electrons could be accelerated with light far enough that they far exceeded the limits of the acceleration observed at individual atoms. The precise movements of the electrons can be precisely controlled via the electric field of the laser light. The new findings of this light-controlled process could help to generate very energetic extreme ultraviolet (XUV) radiation. The experiments and their theoretical modeling, which the scientists describe in the journal Nature Physics, also offer new perspectives for the development of ultrafast, light-controlled nanoelectronics, which could work up to a million times faster than today's electronics.

The process of electron acceleration is reminiscent of a short rally in table tennis. Serve, return and another quick hit, which leads to the point win. It is just as similar when electrons in nanoparticles come into contact with light pulses. An international team, in which Prof. Marc Vrakking from the Max Born Institute (MBI) is involved, has now succeeded in observing the mechanisms and their effects of such a ping-pong game of electrons in nanoparticles under the influence of strong laser light fields.

Fig. 2: Reinforced near fields on a nanosphere of glass. The near fields on the polar axis of the particle are time-dependent, with the time running from bottom right to top left as in the illustrated wave. Along the polarization axis of the laser (along the crests and valleys) the fields show a clear asymmetry in their amplitude. This asymmetry leads to a higher energy gain of the electrons on one side of the nanoparticle compared to the other. In the case shown, the fastest electrons are formed by the maximum field elevation on the back of the particle. The energy of the electrons and their directions of emission are determined in the experiment.
Christian Hackenberger / LMU

For the first time, scientists were able to observe and record in detail the phenomenon of this direct elastic recoil in a collective nanocomposite. The researchers used polarized light for their experiments. In polarized light, the light waves oscillate only along one axis and not in all directions, as in normal light. "Intense radiation pulses can alter or destroy the nanoparticles. Therefore, we prepared isolated nanoparticles in one beam so that fresh nanoparticles were used for each laser pulse. This is crucial for the observation of high-energy electrons, "explains Prof. Eckart Rühl of the Freie Universität Berlin.

The accelerated electrons left the atoms in different directions and with different energies. These trajectories recorded the scientists in a three-dimensional image, with which they determined the energies and the directions of emission of the electrons. "The electrons are accelerated not only by the laser-induced near field, which itself is already significantly stronger than the laser field, but also by interactions with other electrons, which are released from the nanoparticle," describes Prof. Matthias Kling from the Max Planck Institute for Quantum optics in Garching the experiment. Finally, the positive charge of the nanoparticle surface also plays a role. Since all contributions add up, the energy of the electrons can be very high. "The process is complex, but it shows that there is still a lot to discover in the interaction of nanoparticles with strong laser fields," adds Kling.

The movements of electrons can also produce pulses of extreme ultraviolet light, namely whenever the electrons strike the surface again, but instead of being ricocheted, absorbed and emitting light. Extreme ultraviolet light is especially interesting for biological and medical research.

"According to our findings, the recombination of the electrons on the nanoparticles can reach energies of the emitted photons that are up to seven times the limit that was previously observed for individual atoms," explains Prof. Thomas Fennel from the University of Rostock. The proof of the collective acceleration of the electrons with the nanoparticles offers great potential. "This results in promising new applications in future, light-controlled, ultra-fast electronics, which could work up to a million times faster than conventional electronics," Matthias Kling is convinced.

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Publications since 2025

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A1-P-2025.01
Melting, bubblelike expansion, and explosion of superheated plasmonic nanoparticles

S. Dold, T. Reichenbach, A. Colombo, J. Jordan, I. Barke, P. Behrens, N. Bernhardt, J. Correa, S. Düsterer, B. Erk, T. Fennel, L. Hecht, A. Heilrath, R. Irsig, N. Iwe, P. Kolb, B. Kruse, B. Langbehn, B. Manschwetus, P. Marienhagen, F. Martinez, K.-H. Meiwes-Broer, K. Oldenburg, C. Passow, C. Peltz, M. Sauppe, F. Seel, R. M. P. Tanyag, R. Treusch, A. Ulmer, S. Walz, M. Moseler, T. Möller, D. Rupp, B. v. Issendorff

Physical review letters 134 (2025) 136101/1-7

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A3-P-2025.01
Second-harmonic generation in OP-GaAs0.75P0.25 heteroepitaxially grown from the vapor phase

L. Wang, S. R. Vangala, S. Popien, M. Beutler, J. M. Mann, V. L. Tassev, E. Büttner, V. Petrov

CrystEngComm 27 (2025) 1373-1376

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A3-P-2025.02
Diode-pumped Kerr-lens mode-locked Yb:MgWO4 laser

H.-Y. Nie, Z.-L. Lin, P. Loiko, H.-J. Zeng, L. Zhang, Z. Lin, G. Z. Elabedine, X. Mateos, V. Petrov, G. Zhang, W. Chen

Optics Letters 50 (2025) 1049-1052

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A3-P-2025.03
Growth, anisotropy, and spectroscopy of Tm3+ and Yb3+ doped MgWO4 crystals

G. Z. Elabedine, R. M. Solé, S. Slimi, M. Aguiló, F. Díaz, W. Chen, V. Petrov, X. Mateos

CrystEngComm 27 (2025) 1619-1631

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A3-P-2025.04
Growth, structure, spectroscopic, and laser properties of Ho-doped yttrium gallium garnet crystal

S. Slimi, H. Yu, H. Zhang, C. Kränkel, P. Loiko, R. M. Solé, M. Aguiló, F. Díaz, W. Chen, U. Griebner, V. Petrov, X. Mateos

Optics Express 33 (2025) 2529-2541

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A3-P-2025.05
Growth, spectroscopy and laser operation of disordered Tm,Ho:NaGd (MoO4)2 crystal

G. Z. Elabedine, Z. Pan, P. Loiko, H. Chu, D. Li, K. Eremeev, K. Subbotin, S. Pavlov, P. Camy, A. Braud, S. Slimi, R. M. Solé, M. Aguiló, F. Díaz, W. Chen, U. Griebner, V. Petrov, X. Mateos

Journal of Alloys and Compounds 1020 (2025) 179211/1-12

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A3-P-2025.06
Kerr-lens mode-locked, diode-pumped Yb,Gd:YAP laser generating 23 fs pulses

H.-Y. Nie, P. Zhang, P. Loiko, Z.-L. Lin, H.-J. Zeng, G. Zhang, Z. Li, X. Mateos, H.-C. Liang, V. Petrov, Z. Chen, W. Chen

Optics Express 33 (2025) 11793-11799

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A3-P-2025.07
Nanoindentation and laser-induced optical damage tests of CdSe nonlinear crystals

G. Exner, A. Carpenter, K. Cissner, A. Hildenbrand-Dhollande, S. Schmitt, A. Grigorov, M. Piotrowski, S. Guha, V. Petrov

Journal of the Optical Society of America B 42 (2025) A10-A14

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A3-P-2025.08
Phase-matching properties of AgGa(Se1-xTex)2 for SHG of a CO2 laser

K. Kato, V. Petrov, K. Miyata

Proceedings of SPIE 13347 (2025) 133470S/1-4

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A3-P-2025.09
Phase-matching properties of ZnSiAs2 in the mid-IR

T. Okamoto, N. Umemura, K. Kato, V. Petrov

Proceedings of SPIE 13347 (2025) 133470C/1-5

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A3-P-2025.10
Direct generation of 3.5 optical-cycle pulses from a rare-earth laser

N. Zhang, Y. Wang, H. Ding, F. Liang, Y. Zhao, J. Xu, H. Yu, H. Zhang, V. Petrov

Optics Letters 50 (2025) 3150-3153

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A3-P-2025.11
Power scaling of a non-resonant optical parametric oscillator based on periodically poled LiNbO3 with spectral narrowing

S. Das, T. Temel, G. Spindler, A. Schirrmacher, I. B. Divliansky, R. T. Murray, M. Piotrowski, L. Wang, W. Chen, O. Mhibik, V. Petrov

Optics Express 33 (2025) 5662-5669

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A3-P-2025.12
Sub-40-fs diode-pumped ytterbium-doped mixed rare-earth calcium oxoborate laser

H.-J. Zeng, Z.-L. Lin, H. Lin, P. Loiko, L. Zhang, Z. Lin, H.-C. Liang, X. Mateos, V. Petrov, G. Zhang, W. Chen

Optics Express 33 (2025) 17965-17975

URL, DOI or PDF

A3-P-2025.13
Spectroscopy and SESAM mode-locking of a disordered Yb:Gd2SrAl2O7 crystal

H.-J. Zeng, Z.-L. Lin, P. Loiko, F. Yuan, G. Zhang, Z. Lin, X. Mateos, V. Petrov, W. Chen

Optics Express 33 (2025) 15057-15066

URL, DOI or PDF

A3-P-2025.14
Watt-level, 1.6 ps χ(2)-lens mode-locking of an in-band pumped Nd:LuVO4 laser

H. Iliev, V. Aleksandrov, V. Petrov, L. S. Petrov, H. Zhang, H. Yu, I. Buchvarov

Optics Express 33 (2025) 17773-17781

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A3-P-2025.15
Refined phase-matching predictions for AgGa1-xInxS2 mixed chalcopyrite crystals

K. Kato, K. Miyata, V. Petrov

Journal of the Optical Society of America B 42 (2025) A6-A9

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A3-P-2025.16
35-fs diode-pumped mode-locked ytterbium-doped multi-component alkaline-earth fluoride laser

Z. Zhang, Z.-Q. Li, P. Loiko, H.-J. Zeng, G. Zhang, Z.-L. Lin, S. Normani, A. Braud, F. Ma, X. Mateos, H.-C. Liang, V. Petrov, D. Jiang, L. Su, W. Chen

Optics Letters 50 (2025) 1835-1838

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A3-P-2025.17
Diode-pumped few-optical-cycle laser based on an ytterbium-doped disordered strontium yttrium borate crystal

H. Zeng, Z. Lin, S. Sun, P. Loiko, H. Lin, G. Zhang, Z. Lin, C. Mou, X. Mateos, V. Petrov, W. Chen

Optics Letters 50 (2025) 2203-2206

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A3-P-2025.18
Refined Sellmeier and thermo-optic dispersion formulas for CdGeAs2

K. Kato, K. Miyata, V. Petrov

Journal of the Optical Society of America B 42 (2025) A24-A28

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A3-P-2025.19
Diode-pumped mode-locked Yb:Ca3La2(BO3)4 laser generating 35 fs pulses

H.-J. Zeng, Z.-L. Lin, G. Zhang, Z. Pan, P. Loiko, X. Mateos, V. Petrov, H. Lin, W. Chen

Optics Express 33 (2025) 22988-22996

URL, DOI or PDF